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They did not have the benefit of cheap, off the shelf, mass produced batteries. Bronze is a relatively hard alloy of copper and tin, better suited for the purpose than the much softer copper enabling improved durability of the weapons and the ability to hold a cutting edge.For many years the telegraph, and later the telephone, industries were the only consumers of batteries in modest volumes and it wasn't until the twentieth century that new applications created the demand that made the battery a commodity item. The use of bronze for tools and weapons gradually spread to the rest of the World until it was eventually superceded by the much harder iron.
Volta's pile was at first a technical curiosity but this new electrochemical phenomenon very quickly opened the door to new branches of both physics and chemistry and a myriad of discoveries, inventions and applications.
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Initially inspired by the development of batteries, it covers technology in general and includes some interesting little known, or long forgotten, facts as well as a few myths about the development of technology, the science behind it, the context in which it occurred and the deeds of the many personalities, eccentrics and charlatans involved.